Bis{1-[(1H-benzimidazol-2-yl)methyl]-1H-imidazole-κN 3}bis(3,5-dicarboxybenzoato-κO 1)zinc octahydrate
نویسندگان
چکیده
In the title complex, [Zn(C(9)H(5)O(6))(2)(C(11)H(10)N(4))(2)]·8H(2)O, the Zn(II) ion exhibits site symmetry 2. It shows a distorted tetra-hedral coordination defined by two N atoms from two symmetry-related 1-[(1H-benzimidazol-2-yl)meth-yl]-1H-imid-azole ligands and by two O atoms from two symmetry-related monodeprotonated 3,5-dicarb-oxy-benzoate anions. In the crystal, complex mol-ecules and solvent water mol-ecules are linked through inter-molecular O-H⋯O, O-H⋯N, and N-H⋯O hydrogen bonds into a three-dimensional network.
منابع مشابه
Bis{1-[(1H-benzimidazol-1-yl)methyl]-1H-imidazole-κN 3}bis(3,5-dicarboxybenzoato-κ2 O 1,O 1′)nickel(II) octahydrate
In the title complex, [Ni(C9H5O6)2(C11H10N4)2]·8H2O, the Ni(II) ion exhibits site symmetry 2. It has a distorted octa-hedral coordination defined by two N atoms from two symmetry-related 1-[(1H-benzimidazol-1-yl)meth-yl]-1H-imidazole ligands and four O atoms from two symmetry-related 3,5-dicarb-oxy-benzoate anions. In the crystal, the complex mol-ecules and solvent water mol-ecules are linked v...
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متن کاملcatena-Poly[[[bis(thiocyanato-κN)zinc(II)]-μ-1,2-bis{[2-(2-pyridyl)-1H-imidazol-1-yl]methyl}benzene] 0.28-hydrate]
The title one-dimensional coordination polymer, {[Zn(NCS)(2)(C(24)H(20)N(6))(2)]·0.28H(2)O}(n), was obtained by the reaction of Zn(OAc)(2)·2H(2)O, KSCN and 1,2-bis-{[2-(2-pyrid-yl)-1H-imid-azol-1-yl]meth-yl}benzene (hereafter L). The Zn(II) ion shows a distorted octa-hedral coordination geometry and is coordin-ated by two N atoms from two SCN(-) anions and four N atoms from two organic ligands....
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